http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0071082-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0efa077d881a96aeb1e29b21ef1bbb58 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F8-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01B1-125 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08K5-0091 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08L49-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08K5-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F8-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01B1-12 |
filingDate | 1982-07-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_44046b3d717769b23b02f06c21e74411 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1eb67da35069a8b097c5bbe39b5e5d65 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4920a79dc0144d415fe8298b4362c8b3 |
publicationDate | 1983-02-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | EP-0071082-A1 |
titleOfInvention | Process for the preparation of polyenes stable in air and electrically conductive, and their use in the electrotechnique and in rendering plastics antistatic |
abstract | The invention relates to a process for producing air-stable, electrically conductive polymeric systems with electrical conductivity values greater than 10 -2 S / cm, using a polyene of the general formula (1): wherein n = 5 to 1000, R and R 'can be the same and different with R and R' = H, C 1 -C 5 alkyl, cycloalkyl, aryl, CN, F, Cl, Br, or R and R '= -CH 2 -, which is cyclically linked by alkylidene bridges of the form CH 2 m with m = 1 to 2, or a polycyclic aromatic system which is linked to the double bond of the polyene (I) in the peri-position, preferably in a solvent with a transition metal complex compound of the general formula (II): where M = transition metal of the 1st, 4th, 5th, 6th, 7th or 8th subgroup of the periodic system of the elements L 1 = (CO), L 2 = Cl, Br, I, H, (CS), (CO), M'R 1 R 2 R 3 with R 1 , R 2 and R 3 = identical or different and R 1 , R 2 and R 3 = F, Cl, Br, H, C 1 -C 6 alkyl , Cycloalkyl, aryl, C 1 -C 6 alkoxy, aryloxy and M '= P, As, Sb and I and x and y = 1 to 20, polymers with the partial emergence of ligands L 1 or L 2 , the structural units of the general formulas (III), (IV) and (V) contained in copolymerized form, in which M is a transition metal indicated above, L 'and L 2 are the ligands mentioned above and x' = 1 to 6 and y '= 0 to 6 and these polymers optionally with conventional complexing agents such as AsF 5 , SbF 5 , SbCl 5 , FeCl 3 , PCl 5 + Cl 2 , PF 5 + NOF, PF 5 + NO 2 F, BF 4 + NOF, Li, Na, K, Rb or Cs.n n n The electrically conductive polymers obtained can be used in electrical engineering for the production of solar cells, for the conversion and fixation of radiation and for the production of electrical and magnetic switches and for the antistatic finishing of plastics. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4845513-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4847639-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4851808-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4804974-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-3608887-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4870388-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-8505728-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-3609456-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0149133-A2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4983993-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0149133-A3 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4783369-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4447583-A |
priorityDate | 1981-07-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 88.