http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0042985-A2

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filingDate 1981-06-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_469a4fcc053e5f0b0cbbd465cec57573
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3a6d5fc276b5f05592f32cf6a50a7043
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publicationDate 1982-01-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0042985-A2
titleOfInvention Process for the preparation of vinylaromatic polymers modified by rubbers
abstract The invention relates to a process for the continuous production of rubber-modified polymers of vinyl aromatics, which is carried out in bulk or solution in more than 2 reaction zones. Here, a monomeric aromatic vinyl compound and a rubber-like polymer, in a proportion of 3 to 16% by weight, based on monomers (s), in the absence of radical initiators, but in the presence of mercaptans as chain transfer agents at temperatures of 80 to 180 ° C. a first reaction zone with stirring to a maximum conversion, Umax, based on monomer, polymerized that the relationship is sufficient [K = amount of rubber in% by weight, based on monomers (s)].n n n In a second reaction zone, polymerization is continued with conversions up to about 50% by weight and then a chain transfer agent is introduced in amounts of 0.01 to 0.2% by weight, based on vinyl aromatic monomer, with a conversion of up to less than 85% by weight, based on monomers (s), is optionally further polymerized in more than one reaction zone. The polymer is freed from vinylaromatic monomers and, if appropriate, from the solvent in a degassing zone, the latter being returned to the process.n n n The claimed process allows products with a good gloss and, at the same time, a good mechanical level to be produced, which can be used in conventional fields of application.
priorityDate 1980-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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