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filingDate 1981-04-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1981-10-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0037616-A1
titleOfInvention Process for the preparation of polymers of conjugated dienes or of copolymers of conjugated dienes with each other or with a vinylaromatic compound
abstract Process for producing polymers of conjugated dienes and copolymers of conjugated dienes, either with each other or with vinyl aromatic compounds.n n n a) d'un composé organique d'un métal du groupe III A de la classification périodique des éléments du tableau de Mendéléev répondant à l'une des formules suivantes:n MeI MR 1 R 2 R 3 R 4 Men[MR 1 R 2 R 3 R 4 ] 2 MR 1 R 2 R 3 MeIOMR 1 R 2 b) et d'un plusieurs composés donneurs d'électrons renfermant un ou plusieurs hétéroatomes, net à ajouter en cours de polymérisation un composé d'un métal de transition des groupes 1 B à 7B et 8 ou un composé du magnésium de formule Mg(A) 2 .It consists in polymerizing or copolymerizing the monomers in solution in an inert solvent at a temperature between 20 ° and 200 ° C in the presence of a catalytic system consisting of the reaction product: a) of an organic compound of a metal from group III A of the periodic table of elements in the Mendéléev table corresponding to one of the following formulas: MeI MR 1 R 2 R 3 R 4 Men [MR 1 R 2 R 3 R 4 ] 2 MR 1 R 2 R 3 MeIOMR 1 R 2 b) and of a plurality of electron donor compounds containing one or more heteroatoms, and in the course of polymerization, adding a compound of a transition metal from groups 1 B to 7B and 8 or a magnesium compound of formula Mg (A) 2 .
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