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filingDate 1980-08-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9f0a8be66377b4b21b65b1709b578f98
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publicationDate 1981-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0025890-A1
titleOfInvention Process for the hydroxylation of low-chain aliphatic mono- or diolefines
abstract 3-chloro-2-methylpropene-1, straight-chain or branched, unsubstituted or already substituted by 1 to 2 hydroxyl groups monoolefins with 4 to 7 carbon atoms and terminal or internal double bond, straight-chain or branched, unsubstituted or already substituted by 1 or 2 hydroxyl groups, monoolefins with 8 up to 10 carbon atoms and internal double bond or straight-chain or branched diolefins with 4 to 10 carbon atoms are reacted at a temperature between 30 and 80 ° C with less than 2 moles of formic acid and less than 2 moles of hydrogen peroxide, in each case per mole of double bond to be hydroxylated. Formic acid with a concentration between 20 and 100 percent by weight and hydrogen peroxide with a concentration of less than 50 percent by weight are used. The concentration of hydrogen peroxide in the aqueous phase of the reaction mixture is kept below 15 percent by weight throughout the reaction. From the olefins used, the corresponding diols or polyols are formed in high yields directly within acceptable reaction times.
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