Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0efa077d881a96aeb1e29b21ef1bbb58 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C249-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C239-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C309-66 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C309-66 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C239-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C251-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C249-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-02 |
filingDate |
1994-05-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e5e00d17766a7c68ed89c1740b9f6400 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_567d97e551071391e7195c7633c3296c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_69a372fa954e7bfd7ea8346a954f9ece http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7332c154f997a02d44c0e4709f0a849f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_74c0df973b8d64d70f22dbb9c8c5be18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_247bcf5a2c8805051c97991e68961e9a http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_185741e5f2b496ee0478b652ad61e849 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_989440272453cfaf28ed82a8e40563b9 |
publicationDate |
1995-06-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
DE-4415887-A1 |
titleOfInvention |
Process for the preparation of O-phenoxyalkyloximes and O-phenoxyalkylhydroxylamines |
abstract |
A process is disclosed for producing isomer mixtures from O-phenoxyalkylhydroxyl amines Ia: H2N-O-CH2-CH(R<1>)-O-Ar and Ib: H2N-O-CH(R<1>)-CH2-O-Ar (wherein R<1> represents alkyl, Ar where appropriate a substituted phenyl) and the corresponding salt mixtures. This process involves the following steps: (a) an isomer mixture of O-(2-hydroxyethyl)-oximes (IIa) and (IIb) (in which R<2> is an alkyl and R<3> is an alkyl or alkoxy, or R<2> and R<3> together with the common C atom form a 5-7 member ring) is converted by reaction with a sulphonyl halogenide of formula (III): Hal-SO2-R<4> (wherein R<4> represents an organic group and Hal is a halogen) in the presence of a base to form the corresponding sulphonate mixture of (IVa) and (IVb); (b) this sulphonate mixture is reacted in the presence of a base with a phenol of formula (V): HO-Ar to produce a mixture of O-phenoxyalkyloximes of general formulae (VIa) and (VIb); (c) the mixture is hydrolysed in the presence of an acid and, if required, (d) the O-phenoxyalkylhydroxyl amines (Ia) and (Ib) are released from the resulting salts using a mineral base. The O-phenoxyalkylhydroxyl amines (Ia/Ib) and their precursors (VIa/VIb) are important intermediate products for plant protective agents and drugs. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5739400-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-9604237-A1 |
priorityDate |
1994-05-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |