http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-4218841-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c7ad58d3c0b071069a8ee0cb8c8ba2e8 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C17-389 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01D15-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01D15-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C17-38 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C17-389 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C25-08 |
filingDate | 1992-06-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1f699ecc58eecbd9479ddf4943b1dfb6 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_99264b2a79ed018d70ec4b0b07383cbe http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_183f251385f062649d7d31c2461c9531 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bf0485059894684c49d80bdb554333fe http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f70e4edd39820899e126b286a85e204d http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c31b980d2dfe9dc5a6a245cb0dba8fee |
publicationDate | 1993-12-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | DE-4218841-A1 |
titleOfInvention | Process for the separation of mixtures of m- and p-dichlorobenzene |
abstract | Sepn. of mixts. (I) of m- and p-dichlorobenzene (m-DCB, p-DCB) involves treatment in the liquid phase with zeolites. (I) dissolved in a solvent (II) is treated at 20-250 deg.C with a pentasil zeolite (III) with exchangeable H, gp. IA-IIA metal and/or lanthanide metal cations, (II) being 5-15 C cyclic satd. hydrocarbon(s) (IIA), 8-12 C alkyl-aromatic hydrocarbon(s) and/or 6-10 C aromatic halohydrocarbon(s) with 1-3 halogen atoms, except ethylbenzene, chlorobenzene, p-xylene, p-chlorotoluene and dichlorobenzene. Enriched m-DCB is obtd. as filtrate and p-DCB is recovered from (III) by desorption. (III) is pref. Zeta 1, Zeta 3, ZBM 10, Ultrasil, Ultrazet, TZ-01, NU-4, NU-5, AZ-1, pref. ZSM 8, ZSM 5/ZSM 11 intermediates or esp. ZSM 5 and ZSM 11. The amt. is 0.05-2, pref. 0.1-1, esp. 0.2-0l8 pts. (I)/pt. (III). (I) contains 50-70 (wt.)% m-CDB. (II) is (IIA) with 5-12 C, esp. cyclohexane; 8-10 C alkylbenzenes with one to three 1-3 C alkyl gps. contg. a total of max. 4 C, esp. o- or m-xylene or mesitylene; or 6-8 C chlorobenzenes with 1-3 Cl atoms, esp. 1,2,4-trichlorobenzene (IIB) or 3,4-dichlorotoluene; or a mixt. of these. ADVANTAGE - Sepn. of p-DCB from m-DCB is very highly selective and the process is suitable for both batch and continuous operation. |
priorityDate | 1992-06-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 78.