http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-3920570-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_5c24684033fba97d1ad845ce453a57e3 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C12P41-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F9-301 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C12P13-04 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C12P13-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C12P41-00 |
filingDate | 1989-06-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4ea95f696933493fa453aead03b81775 |
publicationDate | 1991-01-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | DE-3920570-A1 |
titleOfInvention | METHOD FOR ISOLATING L-2-AMINO-4-METHYLPHOSPHINOBUTTERIC ACID AMMONIUM SALT FROM AN ENZYMATIC TRANSAMINATION SOLUTION |
abstract | L-2-Amino-4-methylphosphinobutyrin acid (L-PTC) (I) is recovered from the reaction soln. obtd. in enzymatic transamination of 4-(hydrody)(methyl) phosphinyl-2-oxobutyric acid (III), and contg. (I), alpha-keto-glutaric acid (II), residues of (III) and L-glutamic acid (IV), by (a) concentrating the soln., (b) acidifying to pH 4.7-3.2 (4.2-3.7) with H2SO4, (c) sepg. the pptd. (IV), (d) acidifying to pH 2-1 with H2SO4, and extracting (II) and (III), (e) concentrating the aq. phase, bringing to pH 5-7 with NH3, with pptn. of (NH4)2SO4, and (f) recovering (I) from the filtrate by further concn. USE/ADVANTAGE - DL-PTC is a herbicide; (I) is the active form, whilst D-PTC is inactive. (I) is obtd. in high yield (94%). |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5869668-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2018108794-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2018108797-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5767309-A |
priorityDate | 1989-06-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 46.