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filingDate 1986-07-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1992-07-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7392f7ae9129a0a6a851a506ba69a126
publicationDate 1992-07-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-3685523-D1
titleOfInvention METHOD FOR ISOLATING P-HYDROXYBENZALDEHYDE.
abstract Process is for isolation of p-hydroxybenzaldehyde (I) from a reaction mixt. obtd. by oxidn. of p-cresol (II) with O2 or O2-contg. gas in MeOH in presence of NaOH or KOH and a manganese, nickel, chromium or cobalt salt. The process comprises: (i) treating the reaction mixt. with water; (ii) heating theobtd. soln.; (iii) filtering off the obtd. ppte. of hydrated Mn, Ni, Cr or Co oxide; (iv) distilling off MeOH from the filtrate; (v) cooling the remaining aq. soln.; and (vi) allowing (I) to crystallise as the Na or K salt. Alternatively the process comprises: (i') spray-drying the reaction mixt.; (ii') dissolving the soluble components of the residue in hot water; (iii') filtering off the undissolved hydrated Mn, Ni, Cr or Co oxide; and (iv') crystallising (I) as Na or K salt by cooling the filtrate. A further alternative process comprises: (i'') diluting the reaction mixt. with MeOH; (ii'') filtering off the undissolved hydrated Mn, Ni, Cr or Co oxide; (iii'') spray-drying the filtrate; (iv'') dissolving the residue in hot water; and (v'') crystallising (I) as Na or K salt by cooling the soln.
priorityDate 1985-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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