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filingDate 1980-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1982-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-3030734-A1
titleOfInvention METHOD FOR PRODUCING DIGLYCOLIC ACID
abstract Anhydrous diglycolic acid prepn. comprises (a) the hydrolysis of di-n-butyl diglycolate with water and an acid catalyst. The n-butanol generated is distilled off as an azeotrope with water. (b) The aq. diglycolic acid formed in hydrolysis is dehydrated azeotropically with an organic solvent which is water-immiscible or difficultly miscible with water. Diglycolic acid is crystallised from the solvent. The organic solvent is esp. Meiso-BuCO (pref.), Et2CO or di-n-butyl ether. Diglycolic acid itself can be used as catalyst. Diglycolic acid is used as a coagulant for rubber and plastics, as an emulsion breaker for petroleum and as a synthesis intermediate. Over 99 wt.% pure diglycolic acid is obtd. in high yields, e.g. 93%, from di-n-Bu diglycolate, previously burnt as a waste-prod.
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