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filingDate 1979-02-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0d1670d25d181a0cd75b0309bee20002
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publicationDate 1980-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-2904315-A1
titleOfInvention METHOD FOR PRODUCING P-HYDROXYBENZALDEHYDE
abstract In a new process for the prodn. of p-hydroxybenzaldehyde, p-benzyloxy-benzaldehyde derivs. of formula PhCH2OAr are treated with an aq. hydrohalic acid at 70-130 degrees C: Ar is p-formyl-phenyl or its acetal with 1-3C alkyl gps. Reaction temp. is pref. 90-120 degrees C. Suitable hydrohalic acids are HCl and HBr with a concn. of e.g. 5-30 wt.% (the concn. pref. being less than that of the constant boiling mixt. with water). The aq. hydrohalic acid is generally used in an amt. of 3-20 times the wt. of benzoaldehyde deriv. Reaction time is generally 3-20 hrs. Benzyl halide formed as byproduct is advantageously removed from the reaction mixt. by azeotropic distn. with the aq. hydrohalic acid. The single-step process gives prod. of excellent quality in good yields.
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