http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-2653601-A1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c7ad58d3c0b071069a8ee0cb8c8ba2e8 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-46 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-46 |
filingDate | 1976-11-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ee6f51ae8bb4def34eb4aa7ba7ded020 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6ef7aae4a8f7f3ac06e4364824790621 |
publicationDate | 1978-06-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | DE-2653601-A1 |
titleOfInvention | HYDROXYKETONE CONTAINING PERFLUORALKYL GROUPS |
abstract | Prepn. of hydroxyphenyl ketones of formula (I) comprises reacting phenols of formula (II) with acid halides of formula (III) in liq. HF: R2-COX (III). In the formulae, R is a 1-18C alkyl or alkoxy group which is inert w.r.t. HF, or R is 1-5C perfluoroalkyl, halogen, NO2, or a 4C alkynyl gp. which forms a second aromatic ring (sic); R is 1-12C alkyl, 6-12C aryl, 7-14C aralkyl, perfluoroalkyl, an aryl group substd. by one or more 1-12C perfluoroalkyl gps., or a (R)m(OH)n-substd. benzoyl gp; n = 1 or 2; m = 0,1 or 2; R2 is R1 or a COX or (CH2)yCOX group; y = 1-6; X = halogen. Also claimed are new cpds. (I) where n and m are as above, R is 1-5C perfluoroalkyl or H, and R1 is 1-12C alkyl, aryl, perfluoroalkyl or aryl substd. by one or more perfluoroalkyl groups, with the proviso that R1 must be a perfluorinated group when R = H. (I) are used as intermediates for vasodilators and plant protection agents. The process gives high yields (e.g. 75-98%) of products with high purity (e.g. 95-97%). |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5202359-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6608217-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H0684328-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1298129-A2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4593125-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0222961-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-1298129-A3 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S6253937-A |
priorityDate | 1976-11-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 79.