http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-2534558-A1

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C37-16
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C37-16
filingDate 1975-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ff59a439ba15110f8e7548680d6bd867
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cca7ea08179e69e8f07f8df382af0050
publicationDate 1977-02-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-2534558-A1
titleOfInvention PROCESS FOR THE PRODUCTION OF ALPHA, ALPHA'-BIS- (4-HYDROXYPHENYL) - DIISOPROPYLBENZENE
abstract The prepn. of opt. substd. 4-hydroxy-phenyl-isopropylbenzenes comprises reacting opt. alpha-OH- or alpha-alkoxy-substd. isopropylbenzenes having formula (I) (where n is no. 1-3; R1 areopt. different when n = 2 or 3 and denote H, OH or 1-6C alkyl) with opt. substd. phenols. Acid catalysts are used and consists of light-coloured sulphonated polystyrene crosslinked with max. 10(2-4) wt. % divinylbenzene. Process is partic. suitable for condensing alpha,alpha'-dihydroxy-diisopropylbenzenes and their derivs. with phenols to give alpha,alpha'-bis-(4-hydroxyphenyl)-diisopropylbenzenes (II). (II) are starting materials for prodn. of polycarbonates, polyesters and polysulphones. Catalysts cause no corrosion and are easily sepd. High space-time yields are achieved. Yields reach 98% of theoretical. Prods. are highly pure. In an example, 300g/hr alpha,alpha'-dihydroxy-1,4-diisopropylbenzene and 3600 g/hr. phenol were pumped through catalyst bed of 400g ion exchanger having degree of crosslinking 2% and Lovibond colour values 0.5, 0 and 2.1 in red, blue and yellow ranges. alpha,alpha'-Bis-(4-hydroxyphenyl) p-diisopropylbenzene was obtd. in 94% yield. M. pt. 196-197 degrees C (from toluene).
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priorityDate 1975-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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