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filingDate 1975-04-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cf84210e9269cf753c3968973c99c980
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publicationDate 1976-10-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-2516316-A1
titleOfInvention PROCESS FOR THE PREPARATION OF ALKYL- OR CYCLOALKENOANILINE BY STEAM PHASE AMINATION OF ALKYL- OR CYCLOALKENO-PHENOL WITH EXCESS AMMONIA IN THE PRESENCE OF AN ACID CATALYST
abstract Alkyl- or cycloalkenoaniline prepn. by vapour-phase amination of alkyl- or cycloalkeno-phenol with excess NH3 in the presence of an acid catalyst of Al2O3-, Al2O3/-SiO2-, Al2O3/TiO2-, Al2O3/ZrO2-, ZrO2/SiO2 or TiO2/-SiO2-type, takes place at 360-440 degrees C under press. 5-80 bar in the presence of toluene in vol. ratio (alkyl- or cycloalkeno-phenol:toluene) of 1:0.1-1:3. Addn. of toluene as diluent suppresses by-prod. formation and improves process selectivity and conversion. Toluene content of reaction mixt. enables direct azeotropic sepn. of water formed. Recovered toluene can be recycled to reaction without loss.
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priorityDate 1975-04-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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