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filingDate 1972-08-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1974-02-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-2238544-A1
titleOfInvention PROCESS FOR MANUFACTURING REINSTSELEN
abstract Commerical 90.98% Se is purified by zone melting in a continuous melting unit at 450-650 degrees C using air-, oxygen-, or a mixt. of air and 45-55% O2, prehated to 350-450 degrees C, and cond. nitric acid as catalyst. The catalyst is introduced at a rate of 20-30 g HNO3/kg oxidised Se, by passing the air, oxygen or air/oxygen mixt. through a column filled with concd. nitric acid. The Se dioxide is passed continuously through a packed column or fluidized bed in countercurrent to deionized water of spec. resistance >2 Megohm. Se acid soln. is treated with an ion exchanger and high purity Se is pptd. in known manner.
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