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filingDate 1996-12-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5293392c264b1a058e38dd04244a5a9a
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publicationDate 1998-07-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-19654485-A1
titleOfInvention Process for the production of stable 2-hydroxy-4-methylthiobutyric acid (MHA)
abstract Preparation of storage stable 2-hydroxy-4-methylthio-butyric acid (MHA) comprises distillation of a product containing >95 wt.% of a mixture of monomeric and oligomeric components of MHA. Distillation is under reduced pressure and over a time span short enough to avoid formation of by-products. Also claimed is a process for preparing MHA by isolation from a reaction mixture produced as follows; reaction of HCN and methylmercaptopropionaldehyde (MMP); hydrolysis of the obtained cyanohydrin (MMP-CH) with mineral acid; extraction with organic solvent in a liquid-liquid extraction system; evaporation of solvent from the extract; distillation to give a distillate which is chiefly MHA monomers and a bottom product of MHA dimers and oligomers; and regenerating MHA monomers by adding the bottom product to the hydrolysis of MMP-CH and/or MHA amide. Also claimed is the MHA obtained by these processes, containing >95% MHA (calculated as the sum of the monomer, dimer and oligomers), a kinematic viscosity of > 100 mm<2>/s at 25 deg C and a content of <10 mole % monomeric MHA (sic).
priorityDate 1996-12-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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