http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-1951320-A1

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filingDate 1969-10-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9c490f3dcd9f84d64fcd7a0bd62aace5
publicationDate 1970-04-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-1951320-A1
titleOfInvention Process for the cracking of dicyclopentadiene to monocyclopentadiene
abstract Dicyclopentadiene is craked to form cyclopentadiene by (a) heating the dicyclopentadiene in a hydrocarbon solvent at 250-350 degrees C., (b) partly condensing the cracked gaseous mixture leaving the cracking chamber by retaining this gaseous mixture in a condenser for 1-8 secs., and (c) recovering practically pure cyclopentadiene by distillation. Cracking is carried out at 280-320 degrees C., and the retention time in the condenser is 6.6 secs. Recovery of the cyclopentadiene is effected by fractional distillation. The hydrocarbon solvent is a paraffin with a boiling range of 250-350 degrees C., and 80% of the solvent distils at 20 degrees C. to 10 degrees C. higher than the initial b.pt. according to ASTM test D 86-61. The process may be carried out continuously. The gaseous mixt. is partly condensed at a temp. of 45 degrees C. to 100 degrees C., the paraffin being returned to the cracking chamber, and a practically pure cyclopentadiene being recovered by fractional distillation.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-102013204950-A1
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priorityDate 1968-10-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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