http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-1909169-A1

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assignee http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_04650c4315071ee8af7d26e3441a53b1
classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G06K7-14
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-26
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G06K7-14
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-80
filingDate 1969-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2a44b9a6e49fcc8b961ac44d02f83e1c
publicationDate 1970-09-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-1909169-A1
titleOfInvention Process for the preparation of bishydroxyalkyl esters of benzene dicarboxylic acids
abstract Bis-hydroxyalkyl esters of benzene dicarboxilic acids are produced by suspending 1 mole of the acid in nitrobenzene or a nitrobenzene/nitrotoluene mixture and reacting at 80 deg.-200 deg.C (especially 100 deg.-150 deg.C), with 1.7 to 5 moles, (especially 2 to 4 moles), of alkylene oxide in the presence of a soluble catalyst such as an amine, arsine, stibine, phosphine or quaternary ammonium compound. The reaction is stopped when 75 to 98% of the acid has reacted; time required is 10 to 180 minutes. Similar processes exist using different dispersion media. These new media give conversions and the products have a low dialkylene glycol contamination. Polymer prepared from the ester is suitable for tyre cord. The solubility of the ester in the media is high acid concentrations may be used and still give a yield which is entirely soluble. The acid is completely insoluble and separation is easy.
priorityDate 1969-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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