http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-1202270-B
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_4ece3acbea8acdf68fc811ed5070cc5f |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2602-42 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C273-1809 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C275-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C17-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C335-14 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C273-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C275-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C17-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C335-14 |
| filingDate | 1964-03-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_fb5958d3a3b57721d6b8633a14e6ab6b |
| publicationDate | 1965-10-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | DE-1202270-B |
| titleOfInvention | Process for the preparation of substituted norbornylureas |
| abstract | A urea compound of the formula <FORM:1016659/C2/1> in which R, R1 and R2, when taken as individual radicals, are each hydrogen, chlorine, bromine, an alkyl radical having 1 to 4 carbon atoms or chloromethyl, and when taken as a group, R2 is hydrogen, and R and R1 taken together represent a chemical bond ( - ), -CH2-CH = CH-, or -CH2CHCl-CHCl-, and R3 and R4 are each an alkyl radical having 1 to 8 carbon atoms, is made by contacting a thiourea compound of the formula <FORM:1016659/C2/2> stepwise with phosgene in a water-free organic solvent at a temperature in the range of 0 DEG to 80 DEG C. and then with water in aqueous medium at a temperature in the range of 0 DEG to 100 DEG C. in the presence of an acid acceptor. The intermediate thiourea compounds are made by contacting an unsaturated norbornene compound with HSCN generated in situ from a salt of thiocyanic acid and a mineral acid in aqueous media, at temperatures below 150 DEG C. to produce a corresponding norbornyl isothiocyanate which is then reacted with a dialkyl amine HNR3R4 at temperatures below 150 DEG C. Suitable chloro-substituted norbornenes are obtained by reacting 2-chloro-1-propene, 2,3-dichloropropene-1, or vinyl chloride is reacted with cyclopentadiene (which may be obtained by depolymerizing dicyclopentadiene). Detailed examples are given. Reference has been directed by the Comptroller to Specifications 890,540. |
| priorityDate | 1963-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 70.