http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-112017000374-B4

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filingDate 2017-01-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-04-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1e059e94cc8506afeaebf0084bdb701e
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publicationDate 2021-04-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-112017000374-B4
titleOfInvention A slow release, mold protecting and casein-based microsphere coating material and a process for its manufacture
abstract A manufacturing method for a slowly releasing, mold-protecting, casein-based hollow microsphere coating material, characterized in that the manufacturing method comprises the following steps: Step 1: Provision of hexanolactam / SiO 2 -co-modified casein composite emulsion: 2.6-14.6% parts by weight casein, 1.4-9.4% parts by weight triethanolamine and 29.9-57.9% parts by weight deionized water are placed together in a three-necked flask and at a temperature of 50 ° C-70 ° C sufficiently resolved; then 34.1-42.1% parts by weight of aqueous hexanolactam solution and 0.5-1.5% parts by weight of coupling agent are added dropwise at a constant rate; finally, 1.5-3.5% parts by weight of SiO 2 precursors are added dropwise; Allow to react while keeping warm for 1-3 hour (s), allow to cool to room temperature, thus obtaining a hexanolactam / SiO 2 -co-modified casein composite emulsion; Step 2: Provision of slow-releasing, mold-protecting, casein-based hollow microspheres: 4.4-8.4% parts by weight of hexanolactam / SiO 2 -co-modified casein composite emulsion, which is mentioned in step 1, 57.8-69.8% parts by weight of deionized water, 5.8-13.8% Parts by weight of acrylate monomer and 9.7-17.7% parts by weight aqueous ammonium persulfate solution are placed in a three-necked flask, and the mixture is stirred at a temperature of 60 ° C-80 ° C for 1-3 hours; then 2.3-10.3% parts by weight of anti-mold agent are added, the pH is adjusted; Allow the mixture to react while heating and then keeping it warm, stir for 1-9 hours and allow to cool to room temperature, thus slowly releasing casein-based hollow microspheres that protect against molds are obtained.
priorityDate 2016-01-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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