http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-112012001058-B4

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grantDate 2019-08-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2019-08-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-112012001058-B4
titleOfInvention METHOD FOR PRODUCING A TANDEM PHOTOVOLTAIC UNIT
abstract A method of making a tandem photovoltaic device, comprising: forming a bottom cell (104) on a substrate (122), the bottom cell (104) including an n-type layer (114), a p-type layer (120), and therebetween a lower intrinsic layer (116), wherein the p-type layer (120) is provided to be formed as a molybdenum layer, and wherein the thickness of this molybdenum layer is larger than the thickness of the n-type layer (114 ), applying hydrogen plasma on the n-type layer (114) to increase the crystallinity of a p-type layer (112) of an upper cell (102) growing on the n-type layer (114), forming an upper cell (102 ) over the lower cell (104) to form a tandem cell (100), the upper cell (102) comprising an n-type layer (106), a p-type layer (112), and an upper intrinsic layer (110 ), and forming a transparent electrode (1 08) on the n-type layer (106) of the upper cell (102), the lower intrinsic layer (116) comprising a chalcogenide compound containing Cu-Zn-Sn having a kesterite structure of the formula CuZnSn (SSe), where 0 ≤ x ≤ 1; 0 ≤ y ≤ 1; 0≤z≤1; -1 ≤ q ≤ 1, wherein z is controlled so that a band gap of the lower cell (104) is set to be smaller than a band gap of the upper cell (102) and the thickness of the intrinsic layer (116) between 0.2 and 4.0 microns.
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