http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-102014217193-B3

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filingDate 2014-08-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2016-02-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_08f94f7d052f051b52fa63699fa1072d
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d6ec03626289b96f13fe6f0554317f17
publicationDate 2016-02-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-102014217193-B3
titleOfInvention Water-resistant laser-markable multilayer article for bonding to wet surfaces, especially in automotive applications, methods of manufacture and uses
abstract Water-resistant laser-markable multilayer article comprising at least the following layers (1) at least one engraving layer, (2) at least one contrast layer disposed under the engraving layer and (3) at least one adhesive layer comprising the pressure-sensitive adhesive K, disposed under the contrast layer, wherein the pressure-sensitive adhesive K is the crosslinking product of a polymer composition comprising at least the following components (A) at least one polymer component A comprising: (i) greater than or equal to 60% by weight to less than or equal to 80% by weight, based on the content of the polymer component A of at least one component A1, the component A1 comprising: (ia) greater than or equal to 2.5% by weight to less than or equal to 15% by weight, based on the total content of component A1, of at least one monomer a comprising compounds having at least one ethylenically unsaturated bond, each selected such that the Glass transition temperature T G of the corresponding homopolymer of the respective monomer a is at least 0 ° C, wherein at least a portion of the total proportion of the monomer a as at least one monomer a1 comprising compounds having at least one ethylenically unsaturated bond and at least one carboxylic acid group, and (ib) greater than or equal to 85% by weight to less than or equal to 97.5% by weight, based on the total content of component A1, of at least one monomer b selected from the group of acrylic acid esters and / or methacrylic acid esters, each of which is selected such that the glass transition temperature T G of the corresponding homopolymer of the particular monomer b is less than or equal to -30 ° C., wherein the (ia) at least one monomer a and the (ib) at least one monomer b are present in total in a proportion of 100% by weight in the component A1, (ii) greater than or equal to 20% by weight to less than or equal to 40% by weight, based on the content of the polymer component A, of at least one resin component A2, wherein the (i) at least one component A1 and the (ii) at least one resin component A2 are present in total in a proportion of 100 wt .-% in the polymer component A, and (B) at least one crosslinker component B comprising covalently crosslinking bi- or polyfunctional compounds, wherein the (A) at least one polymer component A and the (B) at least one crosslinker component B in total with a content of greater than or equal to 95 wt .-% of the total composition of the polymer composition.
priorityDate 2014-08-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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