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publicationDate 2015-10-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-102012202695-B4
titleOfInvention Process for the preparation of glasses and glass ceramics, LAS glass and LAS glass ceramics and their use
abstract Process for the production of glasses using at least one unavoidable raw material impurity with concentrations of less than 100 ppm of arsenic and antimony-free glass mixtures and as refining agent at least one sulfate compound and SnO 2 , wherein the glass mixture comprising the refining agent is melted in a melting tank (1), is melted in a first region (10) of the melting tank (1) and carried out a primary refining, wherein the first region (10) has an average melting temperature T 1 to T 1> 1560 ° C and a mean residence time of the melt t 1 to t 1 > 2 hours is set, and the proportion of SO 3 formed by decomposition of the sulfate compound is lowered to less than 0.002 wt .-% during the execution of the primary refining, and wherein in a second region (20) of the melting furnace (1) a secondary refining is carried out at temperatures which are 50 ° C and more above the temperature of the primary refining, wherein in the second region (20) an average melting temperature T 2 to T 2 > 1640 ° C and an average residence time of the melt t 2 is set to t 2 > 1 hour.
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