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publicationDate 2013-11-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-102012009181-A1
titleOfInvention New transparent coatings with self-healing properties
abstract Process for the preparation of transparent microcapsules comprising the sequence of the following process steps: a) preparation of a solution of i) 0.1 to 1.0% by weight of ammonium and / or alkali metal chloride, ii) 0 to 0.7% by weight of an aromatic compound Iii) from 0.1 to 3.5% by weight of an amine or amide component selected from an amine or amide having at least two amino groups and iv) from 0.3 to 2 , 0 wt .-% of a protective colloid which is soluble in water and the oil in water emulsion stabilized in water, wherein the total concentration of the aforementioned non-aqueous constituents is 1.5 to 7.2 wt .-%, each based on the total weight of Solution, b) addition of 0.02 to 0.13 wt .-% of an emulsifier combination of an anionic and a nonionic emulsifier in the ratio 1: 3 to 3: 1 c) adjusting the pH of the resulting solution to a value in the interval 2.5 to 6, d) if desired adding a dej selected from octanol and decanol in a concentration of 0 to 0.6% by weight, based on the total weight of the preparation, e) addition of 9 to 42% by weight of at least one hydrophobic material, based on the total weight of the preparation, f Addition of from 0.5 to 13.0% by weight of an aldehyde component chosen from formaldehyde, glutaraldehyde and / or glyoxal, g) Tempering of the mixture obtained at 40 to 70 ° C. for 1 to 5 hours with mixing, so that the H) recovering the microcapsules preferably by filtration, washing and drying and, if desired, classifying and coating materials with such transparent microcapsules.
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