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filingDate 2010-08-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2020-06-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2020-06-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-102010033379-B4
titleOfInvention Mechanically stable, nanoporous moldings, processes for their production and their use
abstract A process for producing an airgel molded body, the pores of which are smaller than 10 μm and the molded body has no cracks with a diameter of at least 10 cm or an area of at least 100 cm 2 and a thickness of at least 0.5 cm, in which i. an open-pore organic foam soaked in a mold with a resorcinol-formaldehyde solution or a phenol-aldehyde solution, ii. gelled between 20 ° C and 100 ° C, then iii. between 20 ° C and 120 ° C at 1.013 bar to form an organic monolith with a density of 0.10 g / cm 3 to 0.55 g / cm 3 , a bending strength greater than 0.55 MPa and an effective thermal conductivity at room temperature and dried in air at 1.013 bar of less than 0.040 W / (m * K), then iv. Is pyrolyzed for 1 to 5 hours at 800 ° C. under a protective gas atmosphere, so that the pyrolyzed monolith has a density of 0.10 g / cm 3 to 0.55 g / cm 3 , a flexural strength greater than 0.68 MPa and at room temperature and in air at 1.013 bar has an effective thermal conductivity of less than 0.060 W / (m * K), and then v. is subjected to a high-temperature treatment above 2200 ° C under a non-oxidizing atmosphere so that the molded body has an effective thermal conductivity of less than 0.420 W / (m * K) at 1.013 mbar and room temperature and at 1.013 mbar and 1500 ° C under a non-oxidizing atmosphere has an effective thermal conductivity of less than 0.800 W / (m * K).
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