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publicationDate 2020-07-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-102008042181-B4
titleOfInvention Equilibration of siloxanes on water-containing sulfonic acid cation exchange resins
abstract Process for the preparation of equilibration products of organosiloxanes by rearrangement of the siloxane bond on a sulfonic acid cation exchange resin, whereby an organosiloxane or an organosiloxane mixture used as starting material is brought into contact with a macro-crosslinked cation exchange resin containing sulfonic acid groups and obtained equilibrated organosiloxanes isolated, characterized in that a cation exchange resin is used, the product P of their specific surface area and their mean pore diameter are P ≥ 2.2 × 10 -3 m 3 / kg and the specific surface area A ≥ 35 m 2 / g and the water content of the sulfonic acid cation exchanger is between 8 and 25 percent by weight, based on the mass of the cation exchanger used, a sulfonic acid cation exchange resin being used which has already been used in a process for reorganizing polydimethylsiloxane compositions Was used, and wherein the amount of the cation exchange resin, which has water within the abovementioned limits, to be used, based on the reaction mixture, is from 8 to 25% by weight.
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