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filingDate 2006-03-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_759e73a5ac40505fe8a744615934a345
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publicationDate 2007-09-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-102006009278-A1
titleOfInvention Amidoadamantanes and process for their preparation
abstract There are 1-formamido-adamantanderivate of formula I. 3, 5 and / or 7-position carry the substituents R 1 , R 2 or R 3 , which have the following meanings: Hydrogen, a linear or branched alkyl, alkenyl or alkynyl group having up to 6 C atoms, an aliphatic or aromatic, cyclic or heterocyclic hydrocarbon radical having up to 10 carbon atoms, and formamides of hydrocarbons from the diamondoid series, for example, diamantane, triamantane, tetramantane and pentamantane, excepting the 1-formamido-3,5-dimethyladamantane. Also described is a process for the direct formamidation or acetamidation of adamantane, adamantane derivatives having the abovementioned substituent meanings or of a hydrocarbon from the series of diamondoids, in which the adamantane, the adamantane derivative or the diamondoid with formamide, acetamide or acetonitrile in concentrated acids, but with the avoidance of SO 3 -containing sulfuric acid or 100% nitric acid.
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