http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-102004008574-B4

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publicationNumber DE-102004008574-B4
titleOfInvention Process for the purification of (meth) acrylic acid from distillative workup by dimeric cleavage
abstract A process for purifying (meth) acrylic acid with a process step for working up a composition Z1 comprising (meth) acrylic acid, water, (meth) acrylic acid dimers, protoanemonin, maleic acid and maleic anhydride, comprising the following steps: a) feeding the composition Z1 into a dimer gap reactor and cleavage of the (meth) acrylic acid dimers at a temperature in a range of 50 to 300 ° C; b) removing the overhead product of the dimer gap reactor as a composition Z2 and a bottoms product of the dimer gap reactor as a composition Z3; c) separating (meth) acrylic acid from the composition Z2 by converting the (meth) acrylic acid into the gas phase, whereby a (meth) acrylic acid-based composition Z4 is obtained as a separated product.
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