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publicationDate 1991-02-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DD-287376-A7
titleOfInvention METHOD FOR AVOIDING HYDROGENATION IN HIGH PRESSURE POLYMERIZATION
abstract Process for avoiding hydrogenation in high-pressure polymerization. In the polymerization of ethylene and / or ethylene vinyl acetate monomer mixtures in the presence of hydrogen as a molecular weight regulator, the hydrogenation is pushed back by directly before the start of the polymerization or copolymerization for 24 to 72 hours, a "prepolymerization" of a polymer of 80 to 90 * ethylene and 20 to 10 * vinyl acetate and a melt index at 463 K of 1 to 10 g / 10 min. This results in a sealing of the active centers along the reactor inner wall. The "seal" is repeated with a rise in the rate constant of the hydrogenation to ko0,20 * after technical shutdowns or prophylactically after a certain polymerization time.
priorityDate 1986-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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