http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DD-283633-A5

Outgoing Links

Predicate Object
assignee http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_3bfedd8ba4800708cecfd357707f8f67
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-53
filingDate 1988-10-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_af93e6e6a159397ccfc70773b0a9025b
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_dd146b9172070ea2fdbfa675017d77bb
publicationDate 1990-10-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DD-283633-A5
titleOfInvention METHOD FOR PRODUCING SOLUBLE CYCLOALKYL PHOSPHINOXIDES
abstract The invention relates to a process for preparing gesaettigten Cycloalkylphosphinoxiden by catalytic hydrogenation of analogous Arylphosphinoxiden in the presence of a straegerfreien Pt / Rh bimetallic catalyst with mild reaction compounds (30 to 40C) and low hydrogen pressures (1 to 3 MPa) in an organic solvent mixture (ethanol / glacial acetic acid ). The process which leads to high yields has the advantage of preserving the optical activity of optically active starting materials and allows the preparation of basic phosphines which can be used in versatile ways as ligands for homogeneous hydrogenations and for asymmetric syntheses {cycloalkylphosphine oxide; catalytic hydrogenation; aryl phosphine oxide; basic phosphine; Ligand for homogeneous hydrogenation; asymmetric synthesis; carrier-free Pt / Rh bimetallic catalyst}
priorityDate 1988-10-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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