http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CZ-256394-A3

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assignee http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_36c7e6417df7d3a93390112f3b4a70b5
classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-14
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C57-03
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C57-03
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C51-14
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22
filingDate 1994-10-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_601be0d9bf0099129121d4b8303d84bf
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_46215852e073e8687e26f92c8a6c57db
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b460688a2fefbee0ee99b6b6c220a4b6
publicationDate 1995-09-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CZ-256394-A3
titleOfInvention Hydroxycarbonylation process of butadiene
abstract The present invention relates to the hydroxycarbonylation of butadiene and/or of its derivatives to pentenoic acids, by reaction with carbon monoxide and water. More precisely, it consists of a process for the hydroxycarbonylation of butadiene and of its derivatives by carbon monoxide and water, at a pressure greater than atmospheric pressure and in the presence of a palladium catalyst which is soluble in the reaction mixture, characterised in that: - the reaction is carried out in the presence of crotyl chloride, in a proportion of at least two mol per mole of palladium, - the palladium is found in pi -crotyl complex form, - the water present in the reaction mixture represents an amount less than or equal to 20 % by weight with respect to the weight of the reaction mixture. The pentenoic acids lead by hydroxycarbonylation to adipic acid which is one of the base compounds in the preparation of polyamides-6,6.
priorityDate 1993-10-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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