http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-115043881-A

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filingDate 2022-07-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f13102fb7c38d1b717762f2dde35d140
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publicationDate 2022-09-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-115043881-A
titleOfInvention A metal ion complex fluorescent probe and its preparation and application in the detection of chloroform gas molecules
abstract The invention provides a metal ion complex fluorescent probe capable of detecting chloroform gas molecules and a preparation method thereof. The molecular formula of the fluorescent probe is MnBr 4 (C 19 H 18 P) 2 , which is brominated by methyl triphenyl bromide. obtained by the coordination reaction between phosphine and manganese bromide, the unit cell structure consists of one [MnBr 4 ] 2- anion center and two [(C 6 H 6 ) 3 P(CH 3 )] + cationic ligands, belonging to Monoclinic crystal system, with good photoluminescence and photoluminescence properties. When the fluorescent probe encounters chloroform gas, chloroform molecules can diffuse into the crystal structure and form C 39 H 37 Br 4 MnP 2 Cl 3 , the structure becomes trigonal, and the luminescence performance is quenched. High temperature can promote the desorption of chloroform molecules in C 39 H 37 Br 4 MnP 2 Cl 3 and effectively restore the luminescence properties of the complexes. Therefore, the fluorescent probe of the present invention can not only detect chloroform gas molecules by two convenient ways of photoluminescence and electroluminescence, but also has the characteristic of being used repeatedly for many times.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-115651019-A
priorityDate 2022-07-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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