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filingDate 2022-07-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_caa5bd3082f2aef72202ddd44b1ce5bb
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publicationDate 2022-08-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-114957295-A
titleOfInvention A kind of novel open framework silver bromine compound, its preparation method and application
abstract The invention discloses a novel open-frame silver bromide compound. The chemical formula of the compound is pIm[(Hmta) 2 (NH 3 )Ag 8 Br 9 ], wherein pIm is a 1-propyl-3-methylimidazolium cation, Hmta is hexamethylenetetramine. The structure of the new open-framework silver bromide compound is a three-dimensional open-framework structure. The [Ag 8 Br 9 ]-infinite anion layer is extended into a three - dimensional hybrid framework through Hmta connection, and the pIm + cations are located in the pores to balance the charge of the framework. It is found through experiments in the present invention that the compound exhibits a special fluorescence double emission phenomenon, and the emission peaks are respectively located at 516 nm and 725 nm. The compound exhibits obvious thermo-fluorescence discoloration in the temperature range of 80-300 K, and the intensity ratio of the emission peaks located at 516 nm and 725 nm has a good linear relationship with temperature in the temperature range of 100-200 K, which is a A sensitive ratiometric fluorescent temperature sensing material.
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