abstract |
The invention discloses a method for preparing aromatic ester compounds without metal-catalyzed C(CO)-C oxidation cleavage of aromatic ketones. The method uses TBHP as an oxidant, and in the presence of an iodine source and TBAB, the reaction can be stirred at room temperature. A variety of different aromatic ester compounds are obtained. The method does not need to use metal catalysts and bases, and has the advantages of mild and simple reaction conditions, wide adaptability of reaction substrates, and high yield of target products. |