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filingDate 2022-05-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-12-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-12-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-114874450-B
titleOfInvention Preparation method and application of a bifunctional mesoporous zirconium-based organic framework material
abstract The invention discloses a preparation method and application of a bifunctional mesoporous zirconium-based organic framework material, and relates to the field of catalyst preparation. The preparation method comprises the steps of: reacting 2-aminoterephthalic acid and salicylaldehyde to obtain 2-(2-hydroxybenzylidene amino) terephthalic acid; said 2-(2-hydroxybenzylidene amino) terephthalic acid Formic acid and cobalt salt react to obtain Co(II)-NO-BDC; Zirconium salt, 2-sulfonic acid terephthalic acid and described Co(II)-NO-BDC react to obtain Co(III) in the solution containing F127 /SO 3 H‑mUIO‑66, which is the bifunctional mesoporous zirconium-based organic framework material. The bifunctional mesoporous zirconium-based organic framework material prepared by the present invention not only has a Bronsted acid active center, but also has a Co(III) catalytic active site, which has good catalytic performance in the hydration reaction of alkynes in aqueous media and can be reused repeatedly.
priorityDate 2022-05-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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