http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114775052-A

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filingDate 2022-03-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_45dbee77521b502acaebb865c7a448f5
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publicationDate 2022-07-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-114775052-A
titleOfInvention Thulium-dysprosium co-doped bromide mid-infrared laser crystal, preparation method and application thereof
abstract The invention discloses a thulium-dysprosium co-doped low-phonon energy bromide laser crystal for 4-5 micron all-solid-state lasers and a preparation method thereof, and relates to the field of mid-infrared laser materials and devices. The molecular formula of the crystal is M(Tm x Dy y Pb 1‑x‑y ) 2 Br 5 , wherein M is a metal element K, Rb, Tl, the value range of x is: 0.01≤x≤0.1, and the value range of y is: 0.001≤y≤0.05. In the laser crystal, thulium ions are used as sensitizing ions, which absorb the energy of commercial semiconductor lasers in the near-infrared band and transmit them to dysprosium ions. Dy 3+ : 6 H 11/2 → 6 H 13/2 transition is achieved by using dysprosium ions as active ions to obtain high-efficiency laser output in the 4-5 micron wavelength band. The low phonon energy M(Tm x Dy y Pb 1‑x‑y ) 2 Br 5 crystal has excellent lasing properties and can be directly pumped by commercial LDs, enabling the miniaturization of dysprosium-activated mid-infrared lasers.
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