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filingDate 2022-04-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_24c3eff2769431789f630f45e915dc4a
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publicationDate 2022-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-114752952-A
titleOfInvention A kind of electrocatalytic nitrogen fixation device and method for simultaneously generating nitric acid and ammonia dual products
abstract The invention discloses a bidirectional electrocatalytic nitrogen fixing device and method for simultaneously generating nitric acid and ammonia. Based on an improved H-type electrolytic cell, NOx gas is reduced to NH3 at the cathode and oxidized to NO3 at the anode , thereby realizing harmful exhaust gas. Efficient and harmless treatment and high-value utilization of NOx . The working electrode catalyst in the electrolysis system of the invention is prepared by the methods of physical deposition and chemical growth at the same time, the carbon paper is uniformly covered with a layer of Cu particles by means of magnetron sputtering, and Ni, Co particles are used to prepare ternary alloy electrocatalysts, and the catalysis of multi-metal and multi-active sites promotes the efficient improvement of the chemical reaction rate. The invention realizes the harmless treatment of NOx gas and the synthesis of ammonia and nitric acid, achieves extremely high ammonia yield and selectivity, and is favorable for high-value resource utilization of pollutants such as nitrogen.
priorityDate 2022-04-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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