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publicationDate 2022-07-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-114716476-A
titleOfInvention Self-assembled monolayer hole transport materials based on carbazole derivatives and their synthesis methods and applications
abstract The invention discloses a self-assembled monomolecular layer hole transport material based on carbazole derivatives, a synthesis method thereof, and an application in an inverted perovskite solar cell. The invention uses carbazole with a rigid conjugated plane as the matrix to ensure the hole transport capability of the molecule; the molecular interface performance is regulated by means of conjugation expansion to reduce the energy loss at the interface; the butylphosphoric acid is used as the anchoring group to achieve Self-assembly of hole transport materials on electrode substrates. The synthesis method of the invention is simple, the synthesis cost is low, and the prepared material can realize the dual functions of hole transport and perovskite interface passivation. When the material is used as a hole transport layer in an inverted perovskite solar cell, it can achieve a photoelectric conversion efficiency of >19% without doping, which has broad application prospects.
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