http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114702684-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_aaadcd534c1edeab62f85ec7991cb759 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G83-008 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C25B11-085 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G83-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C25B11-085 |
| filingDate | 2022-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b3e0ce44abfa8de6ed8a629946a8af85 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_28b83cb620df9bf6b2fb26c60b09bc31 |
| publicationDate | 2022-07-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-114702684-A |
| titleOfInvention | An iodine-functionalized metal-organic framework and its preparation method and application |
| abstract | The invention relates to a metal-organic framework material, in particular to an iodine-functionalized metal-organic framework, a preparation method thereof, and an application in electrocatalytic C-N coupling. The iodine-functionalized metal-organic framework is synthesized by solvothermal synthesis of iodine-containing ligands and nickel acetate tetrahydrate. The present invention synthesizes an iodine-modified metal-organic framework material, which has excellent structural stability. When the material is applied to the electrochemical system, the intramolecular C-N coupling of some amide compounds can be realized by in-situ generation of hypervalent iodine intermediates by losing electrons, and the reaction has excellent catalytic performance. The catalyst can be reused many times without losing its catalytic activity. Compared with the existing catalyst, the usage amount of the catalyst is only half of that of homogeneous catalysis, but it can obtain a comparable catalytic yield. |
| priorityDate | 2022-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 49.