http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114591497-A

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filingDate 2022-01-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2d4489839198e6756d7d6f67bbebcfb4
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publicationDate 2022-06-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-114591497-A
titleOfInvention A kind of method that utilizes macroporous material to catalyze L-lactide to prepare L-polylactic acid
abstract The invention discloses a method for preparing L-polylactic acid by utilizing macroporous material to catalyze L-lactide. The method comprises: (1) mixing the monomer L-lactide and the catalyst three-dimensional ordered macroporous ZIF-8, heating and stirring under vacuum conditions to carry out the reaction; (2) cooling the reactor in ice water to complete the reaction, and using The product was dissolved in dichloromethane, the catalyst was separated by centrifugation, and the product L-polylactic acid was obtained by vacuum drying. The method for preparing L-polylactic acid by heterogeneous catalysis of L-lactide by direct ring-opening polymerization disclosed in the invention utilizes that the catalyst has Lewis acid sites and high specific surface area, the synthesis route is simple, no solvent and co-catalyst are required, and the The energy consumption and investment of the separation section are effectively reduced, the conversion rate of L-lactide is high, and the cyclic polylactic acid with high molecular weight and controllable, and the polymer dispersibility index PDI value is particularly small, has a good application prospect.
priorityDate 2022-01-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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