http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114563376-A

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filingDate 2022-01-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9e3b4300efcd0b5e46776ed98dfd1e50
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publicationDate 2022-05-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-114563376-A
titleOfInvention A Resonance Light Scattering Method for Determination of Organophosphorus Pesticides in Camellia Oil Seed Oil
abstract The invention provides a resonance light scattering method for determining organophosphorus pesticides in Camellia oleifera seed oil. Monocrotophos is used as an organophosphorus pesticide model, and is synthesized based on 5-nitrosalicylaldehyde, o-phenylenediamine and ferric nitrate nonahydrate as substrates. A tetradentate Schiff base-iron(III) metal complex B with dual acceptor properties was developed. The central ion iron (III) of complex B can recognize the phosphate group in the organophosphorus pesticide molecule to coordinate with it; the nitro group (-NO2) on the ligand of complex B can recognize the amino group of monocrotophos (- NH2) and combined with it through hydrogen bonds to form a double-acceptor sandwich complex and aggregate reaction to generate a strong resonance light scattering signal at 300 nm. When the concentration of monocrosin is 0μM-1.1μM, the resonance The light scattering intensity was linearly correlated with the concentration of macrophosphorus, and the linear equation was I=1375.9 c(μM)+527.71. The method was applied to the detection of actual camellia seed oil samples, and the recovery rate was in the range of 97.0%-103.0%, and the relative standard deviation was in the range of 1.5%-3.8%.
priorityDate 2022-01-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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