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filingDate 2022-01-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_73726d88b673bf7c7095595b539a61be
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publicationDate 2022-05-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-114436891-A
titleOfInvention A color-tunable aggregation-induced luminescent material, preparation method and application
abstract A color-tunable aggregation-induced luminescent material, preparation method and application. The luminescent material is prepared from 4-biphenylacetonitrile and 4-diethylaminobenzaldehyde through the condensation reaction of Kenowingel, and has aggregation-induced emission enhancement (AIEE) properties and optical properties that can be adjusted through various light response pathways, It exhibits bright yellow fluorescence in the solid state and exhibits a solvochromic phenomenon. Based on the cyanostyrene skeleton, the color and fluorescence of the luminescent material can be effectively regulated by the photoisomerization process in solution and the photodimerization process in the aggregated state under 420 nm illumination. The yellow fluorescence of the luminescent material can be converted into an aggregation-induced luminescent material with blue fluorescence after protonation of the diethylamine group, and the original state of the luminescent material can be restored after deprotonation. The optical properties of aggregation-induced luminescent materials with blue fluorescence after protonation can be efficiently tuned by photoisomerization and photocyclization processes under UV light irradiation. The invention has simple process, low cost and high yield.
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