http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114392738-A

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filingDate 2022-01-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4ebd1e9fa1db7fb242274ed8f6981e5d
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publicationDate 2022-04-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-114392738-A
titleOfInvention Covalent heteroligand, alkynylated hyperbranched polyethyleneimine mineralization method to modulate gold nanoclusters and methods, applications
abstract The invention provides a covalent hetero-ligand, alkynyl hyperbranched polyethyleneimine mineralization method to modulate gold nano-clusters, methods and applications. The invention can directly, greenly and mildly synthesize gold nanoclusters with near spherical macromolecular heteroligands. Specifically, a certain amount of alkynyl groups were attached to hyperbranched polyethyleneimine by a click-like method to obtain a single-molecule heteroligand, and then mixed with chloroauric acid solution in water or a mixed solvent of water and alcohol for several hours. The magic number gold nanoclusters containing only 8 gold atoms per particle can be directly obtained. These nanoclusters have a large number of active amino groups, which are very stable under normal environmental conditions and are convenient for fluorescent labeling. If the glycidyl ether-terminated polyethylene oxide is further attached to the amino group, the fluorescent nanoclusters that are soluble in both water and oil can be obtained, and show efficient catalysis.
priorityDate 2022-01-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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