http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-113999189-B
Outgoing Links
Predicate | Object |
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classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K2211-1033 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K5-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01L33-502 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D295-03 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D295-03 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09K5-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01L33-50 |
filingDate | 2021-11-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2022-12-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2022-12-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-113999189-B |
titleOfInvention | A fluorescent high phase transition coordination compound and its preparation method and application |
abstract | The invention discloses a fluorescent high-phase transition coordination compound and its preparation method and application. The molecular formula of the coordination compound is (C 6 H 14 NO ) 2 MnCl 4 , belongs to the triclinic crystal system, and the space group is P‑ 1. The Mn atoms are all in the center of the four-coordinated regular tetrahedral configuration, and the crystal structure is stable. The excitation wavelength of the coordination compound is 545nm, a strong emission band appears at 450nm, emits green light, and has fluorescence effect. There are a pair of endothermic peaks and exothermic peaks at 425K and 365K, showing a pair of reversible phase transitions, and the phase transition temperature is as high as 425K. The coordination compound is prepared by utilizing manganese chloride and N-ethylmorpholine through direct hydration synthesis and slow evaporation. The preparation method is simple and the operation is controllable. The coordination compound of the invention can be applied to many fields such as light-emitting diodes, coatings, films, damage detection, building decoration, transportation, military facilities and the like. |
priorityDate | 2021-11-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 27.