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filingDate 2021-10-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3759a2cdbba287ce8008d29987768905
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publicationDate 2021-12-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-113862759-A
titleOfInvention Titanium-based gradient lead dioxide composite electrode material for copper electrodeposition and preparation method thereof
abstract The invention relates to a titanium-based gradient lead dioxide composite electrode material for copper electrodeposition and a preparation method thereof, belonging to the technical field of hydrometallurgy anode plates. The titanium-based gradient lead dioxide composite electrode material for copper electrodeposition sequentially comprises a titanium substrate, a Sn-Ru-Ta-ZrOx oxide bottom layer and beta-PbO from inside to outside 2 -nano SnO 2 Intermediate layer, alpha-PbO 2 -copper coated graphite powder transition layer and beta-PbO 2 -nanometer ZrN-cobalt coats the hollow glass microsphere active layer. The invention also provides a preparation method of the titanium-based gradient lead dioxide composite electrode material for copper electrodeposition. The electrode material provided by the invention is applied to electrodeposited copperIn the electrolytic copper solution which does not contain cobalt ions but contains manganese chloride ions, compared with the traditional Pb-0.06 wt% Ca-1.2 wt% Sn anode, the cell voltage can be reduced by 480mV, the service life is prolonged by more than 3 times, the current efficiency is improved by more than 5%, and the current density can be increased by more than 2 times.
priorityDate 2021-10-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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