http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-113861434-B

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filingDate 2021-09-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-10-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-10-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-113861434-B
titleOfInvention A novel magnesium-based MOF material and a solution processing method for the MOF material
abstract A novel magnesium-based MOF material with the chemical formula Mg 2 (TCPE)(DMA)(CH 3 OH)(H 2 O). The synthesis method is as follows: adding organic ligands 1,1,2,2-tetrakis(4-carboxyphenyl)ethylene (H 4 TCPE) and magnesium nitrate hexahydrate (Mg(NO 3 ) 2 .6H 2 O) into N , N-dimethylacetamide (DMA), methanol (CH 3 OH) and water (H 2 O) in a mixed solvent; the mixed solution is reacted in a solvothermal manner to obtain a colorless bulk single crystal, washed and dried After that, magnesium-based MOFs are obtained. A solution processing method for MOF materials: water is used as a dispersant, and a series of metal-organic framework materials are used as dispersoids; this dispersion system can be used for solution processing to realize different applications of crystalline materials, and can be processed into water-based fluorescent inks. in the field of fluorescent anti-counterfeiting. The novel magnesium-based MOF solid of the present invention exhibits good fluorescent properties, so the material can be prepared into an aqueous fluorescent ink. The solution processing method of the MOF material of the present invention is a solution processing method with simple operation and excellent effect, which can be applied to various magnesium-based metal-organic framework materials.
priorityDate 2021-09-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 43.