http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-113522363-B
Outgoing Links
Predicate | Object |
---|---|
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C02F2305-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-025 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C02F2101-38 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C02F2101-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C02F2101-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02W10-37 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-48 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C02F1-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-0013 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-004 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-023 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1691 |
classificationIPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C02F101-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C02F101-38 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J35-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C02F1-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J37-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J37-32 |
filingDate | 2021-06-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2022-11-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2022-11-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-113522363-B |
titleOfInvention | Preparation method and application of metal ion modified MOF micro/nanostructure in hydrogel |
abstract | The invention discloses a preparation method and application of a metal ion-modified MOF micro/nano structure in a hydrogel, and belongs to the field of organic nano photocatalysis. In the present invention, porphyrin ligands are reacted with metal clusters to obtain porphyrin MOF micro/nano structures, which are then blended with sodium alginate (SA) aqueous solution, freeze-molded, and placed in excess divalent metal salt (M 2+ ) solution for cross-linking and solidification to obtain SA-M 2+ -MOF hydrogel balls. Using the method of coordinating cross-linked metal ions and porphyrin molecules, while effectively modifying the micro/nano structure of MOF, it can be evenly and firmly embedded in the SA hydrogel ball skeleton, and its recyclability can be improved. The method is simple and feasible, and provides an experimental basis for the controllable and overall assembly of organic nanomaterials. The application of the obtained SA‑M 2+ ‑MOF in the photocatalytic degradation of organic dyes was studied, and the results showed that the structure has high photocatalytic activity. It provides the possibility to be widely used in pollution control and energy depletion. |
priorityDate | 2021-06-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 43.