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filingDate 2020-04-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2021-10-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-113497279-A
titleOfInvention Long-cycle rechargeable and dischargeable aqueous aluminum ion battery and preparation method thereof
abstract The invention discloses a long-cycle rechargeable and dischargeable water-based aluminum ion battery and a preparation method thereof, comprising the following steps: (1) Al electrode treatment; (2) preparation of electrolyte; (3) preparation of positive electrode material; (4) preparation of positive electrode material; ) Assembly of the battery: The treated Al electrode is soaked in the electrolyte for 1 to 30 minutes, and the battery is assembled after no bubbles are formed on the surface of the Al electrode. The preparation method of the present invention uses metal aluminum as the negative electrode and polyaniline as the positive electrode material, which effectively solves the problem that the positive electrode material is easily destroyed due to Al 3+ being a high-valent ion or is difficult to be embedded in the positive electrode material due to high electrostatic effect, and the aluminum salt aqueous solution is used as the electrolyte. , The inorganic acid is used as the additive of the electrolyte, and the electrolyte is reasonably modified, which effectively inhibits the formation of a passivation layer on the surface of the aluminum electrode during the battery cycle, improves the stability of the cycle, and prolongs the service life; Discharged water-based aluminum-ion batteries have high cycle stability and long service life.
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