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filingDate 2021-06-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_053504ae94d7b912d6f138f46cfaf8c0
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publicationDate 2021-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-113429388-A
titleOfInvention Blue thermally active delayed fluorescent materials based on trifluoromethylpyridine derivative acceptors and their applications
abstract The invention belongs to the technical field of organic electroluminescent materials, and in particular relates to a class of blue thermally active delayed fluorescence (TADF) materials based on trifluoromethylpyridine derivative acceptors and a preparation method and application thereof. Trifluoromethylpyridine has the advantages of moderate electron withdrawing properties and easy chemical modification, and is a good semiconductor electron acceptor unit. The invention provides a new type of electron acceptor structure trifluoromethyl pyridine unit, constructs D-π-A type blue light TADF material, the intramolecular donor and the acceptor unit are connected by a phenyl π bridge, which can effectively reduce the number of donors. The spatial overlap between the bulk unit HOMO and the acceptor unit LUMO results in a smaller ΔE ST , which promotes reverse intersystem jumping performance, enables fast transitions from T1 to S1 states, and reduces nonradiative transitions of molecules, Improve the luminous efficiency of the material.
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