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filingDate 2021-06-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-08-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-08-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-113368889-B
titleOfInvention A kind of hollow microsphere core-shell catalyst and its preparation method and application
abstract The invention discloses a hollow microsphere core-shell catalyst and a preparation method and application thereof, belonging to the technical field of organic silicon, including the preparation of γ-Al 2 O 3 hollow microspheres, tetraethyl orthosilicate, aluminum oxide, ZSM-5 precursor solution was prepared from tetrapropyl ammonium hydroxide and deionized water, and γ-Al 2 O 3 @ZSM-5 hollow microsphere carrier was prepared from ZSM-5 precursor solution and γ-Al 2 O 3 hollow microspheres; After being immersed in NaCl solution and AlCl 3 solution respectively, the catalyst was crystallized to obtain NaAlCl 4 /γ-Al 2 O 3 @ZSM-5 hollow microsphere core-shell catalyst. The catalyst of the invention has good catalytic effect on the preparation of dimethyldichlorosilane by disproportionation of monomethyltrichlorosilane and trimethylmonochlorosilane, and the yield of dimethyldichlorosilane can reach 70 under the condition of 200 DEG C. %above.
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