http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-113354825-A

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filingDate 2020-03-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2021-09-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-113354825-A
titleOfInvention Zirconium-based metal-organic framework material UiO-66(Zr) and its rapid preparation method and application at room temperature
abstract The invention relates to a zirconium-based metal-organic framework material UiO-66(Zr) and a rapid preparation method and application thereof at room temperature. The preparation method includes: (1) after uniformly mixing a zirconium source and an organic ligand, placing it in methanol and stirring at room temperature , after centrifugation, the supernatant was discarded to obtain a transparent gel state intermediate product; (2) the intermediate product was heated and dried to obtain UiO-66(Zr). Compared with the prior art, the present invention does not involve the use of traditional solvothermal methods such as N,N-dimethylformamide and other toxic organic solvents, and UiO-66(Zr) can be synthesized by stirring and drying at room temperature in methanol. , the conditions are mild, the yield is high, the synthesis time is greatly shortened, and the product purity is extremely high, the step of product activation can be omitted, and the large-scale synthesis of this type of metal-organic framework material is very possible; the adsorption performance of fluoride ions in water is good , which can be applied to the adsorption treatment of fluorine-containing wastewater.
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